Scar from Lion King, and Loki. Because when you think about it, they’re very similar. All they want to do is rule the world and look good whilLoki vs. Scar. 

Hulk vs. Beast. They're both misunderstood nice guys.

Thor vs. Hercules. They're both Demi Gods who have to rise to the occasion to beat the bad guy.

Captain America vs. John Smith. America boys with hearts of gold. Willing to play the sacrifice card to do what's right.

Iron man vs. Emperor Kuzco. They're both rich, self obsessed, and think themselves above others, but that doesn't mean they can't save the day.

Hawkeye vs. Robin Hood. They both have a love for bow and arrows and fall for the girl.

Black Widow vs. Megara from Hercules. They both have shady pasts but in the end they do the right thing to help the hero.

Maria Hill vs. Mulan. Both honorable warriors.

Phil Coulson vs. Zaza from Lion King. He's the bosses right hand man. Loyal and awesome.